<?xml version="1.0" encoding="UTF-8"?>
<rss version="2.0"
	xmlns:content="http://purl.org/rss/1.0/modules/content/"
	xmlns:wfw="http://wellformedweb.org/CommentAPI/"
	xmlns:dc="http://purl.org/dc/elements/1.1/"
	xmlns:atom="http://www.w3.org/2005/Atom"
	xmlns:sy="http://purl.org/rss/1.0/modules/syndication/"
	xmlns:slash="http://purl.org/rss/1.0/modules/slash/"
	>

<channel>
	<title>Failure Analysis</title>
	<atom:link href="http://failure-analysis.info/feed/" rel="self" type="application/rss+xml" />
	<link>http://failure-analysis.info</link>
	<description>Metal and Material Failure Testing Information</description>
	<lastBuildDate>Tue, 06 Jul 2010 14:08:12 +0000</lastBuildDate>
	<language>en</language>
	<sy:updatePeriod>hourly</sy:updatePeriod>
	<sy:updateFrequency>1</sy:updateFrequency>
	<generator>http://wordpress.org/?v=3.0</generator>
		<item>
		<title>Analyzing Contaminants, Stains and Debris – Part 2</title>
		<link>http://failure-analysis.info/2010/07/analyzing-contaminants-stains-and-debris-part-2/</link>
		<comments>http://failure-analysis.info/2010/07/analyzing-contaminants-stains-and-debris-part-2/#comments</comments>
		<pubDate>Tue, 06 Jul 2010 14:00:31 +0000</pubDate>
		<dc:creator>Rob</dc:creator>
				<category><![CDATA[Contaminant Analysis]]></category>

		<guid isPermaLink="false">http://failure-analysis.info/?p=96</guid>
		<description><![CDATA[Abrasive Contaminants A gas transmission compressor shaft in a facility in China began showing excessive wear at the bearing journals during initial mechanical testing (spinning) of the compressor. The plant operator suggested the tin based babbitt bearings were the source of the wear. Our analysis of the bearings showed that the babbitt and bond fully [...]]]></description>
			<content:encoded><![CDATA[<p><strong>Abrasive Contaminants</strong></p>
<p>A gas transmission compressor shaft in a facility in China began showing excessive wear at the bearing journals during initial mechanical testing (spinning) of the compressor. The plant operator suggested the tin based babbitt bearings were the source of the wear. Our analysis of the bearings showed that the babbitt and bond fully met industry specifications. Our analysis also revealed hard abrasive particles, composed of aluminum oxide (alumina) and silicon dioxide (quartz) embedded in the surface of the babbitt (Figures 1 and 2). These materials are consistent with grinding and sanding media, and caused the bearings to act as a cutting tool on the shaft journal surface. Metallographic examination of cross sections taken from the bearing confirmed that these particles were present at the surface only, and not throughout the babbitt layer verifying that they were introduced during the commissioning or initial operation of the compressor rather than during manufacture of the bearings. These results indicated that contamination of the lubrication system feeding oil to the bearings occurred during installation or maintenance by the plant operator’s personnel.</p>
<p><a href="http://failure-analysis.info/wp-content/uploads/2010/07/1-Abrasive-Contaminants.jpg"><img class="aligncenter size-medium wp-image-97" title="1-Abrasive-Contaminants" src="http://failure-analysis.info/wp-content/uploads/2010/07/1-Abrasive-Contaminants-300x236.jpg" alt="Abrasive Contaminants" width="300" height="236" /></a></p>
<p style="text-align: center;">Figure 1 – Embedded silicon dioxide particle in the bearing surface. 450X</p>
<p><a href="http://failure-analysis.info/wp-content/uploads/2010/07/1-Abrasive-Contaminants.jpg"><img class="aligncenter size-medium wp-image-97" title="1-Abrasive-Contaminants" src="http://failure-analysis.info/wp-content/uploads/2010/07/1-Abrasive-Contaminants-300x236.jpg" alt="Abrasive Contaminants" width="300" height="236" /></a></p>
<p style="text-align: center;">Figure 2 &#8211; EDS analyses of the embedded particles indicated a mixture of aluminum oxide (Al and O)<br />
and silicon dioxide (Si and O), or quartz (shown above).</p>
<p><strong>Fingerprints</strong></p>
<p>Fingerprints are usually not a source of what we typically think of as contaminants. However, persperation and the oils from our skin contain chlorine, potassium, sodium and other elements in sufficient concentrations to contaminate and initiate corrosion in sensitive components such as electronic contacts and data storage media. Highly polished parts are also susceptible to cosmetic degradation from fingerprints if no protective clear coat is present. Plating defects such as blisters and poor plating adhesion can result when these “bio-contaminants” are present on parts prior to emersion in the plating bath. This was highlighted in MAI’s recent analysis of blister defects (Figure 3) on a nickel plated exhaust manifold.</p>
<p><a href="http://failure-analysis.info/wp-content/uploads/2010/07/3-blistered-nickel-plating.jpg"><img class="aligncenter size-medium wp-image-99" title="3-blistered-nickel-plating" src="http://failure-analysis.info/wp-content/uploads/2010/07/3-blistered-nickel-plating-300x235.jpg" alt="3 blistered nickel plating 300x235 Analyzing Contaminants, Stains and Debris – Part 2" width="300" height="235" /></a></p>
<p style="text-align: center;">Figure 3 – SEM image of blistered nickel plating. 4000X</p>
<p>Analysis of opened blisters by scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS) revealed the presence of chlorine, potassium, calcium and sulfur in small, but significant, concentrations. Both the plating and pre-plating rinse bath chemistries were well within optimal parameters. Visual examination of rinsed parts which were staged for plating showed no indications of contamination. Examination of these parts by SEM and EDS, however, revealed extensive fingerprint residue which contained the same elementals as that observed in the opened blisters (Figures 4-6).</p>
<p><a href="http://failure-analysis.info/wp-content/uploads/2010/07/4-sem-of-fingerprint.jpg"><img class="aligncenter size-medium wp-image-100" title="4-sem-of-fingerprint" src="http://failure-analysis.info/wp-content/uploads/2010/07/4-sem-of-fingerprint-300x235.jpg" alt="4 sem of fingerprint 300x235 Analyzing Contaminants, Stains and Debris – Part 2" width="300" height="235" /></a></p>
<p style="text-align: center;">Figure 4 – SEM image of fingerprint on rinsed manifold.<br />
Somewhat optically transparent, fingerprints are readily visible in SEM images. 8.0X</p>
<p><a href="http://failure-analysis.info/wp-content/uploads/2010/07/5-sem-image.jpg"><img class="aligncenter size-medium wp-image-101" title="5-sem-image" src="http://failure-analysis.info/wp-content/uploads/2010/07/5-sem-image-300x235.jpg" alt="sem image" width="300" height="235" /></a></p>
<p style="text-align: center;">Figure 5 – SEM image of dark area on the fingerprint shown in Figure 4 at high magnification<br />
showing potassium chloride salt crystals from exuded perspiration and oils. 7000X</p>
<p><a href="http://failure-analysis.info/wp-content/uploads/2010/07/6-eds-analysis.jpg"><img class="aligncenter size-medium wp-image-102" title="6-eds-analysis" src="http://failure-analysis.info/wp-content/uploads/2010/07/6-eds-analysis-300x210.jpg" alt="eds analysis" width="300" height="210" /></a></p>
<p style="text-align: center;">Figure 6 – EDS analysis of crystals shown in Figure 5 composed of sulfur (S), chlorine (Cl at arrow),<br />
potassium (K) and calcium (Ca) in addition to the steel substrate.</p>
<p>Because the plating vendor’s customer set particularly demanding cosmetic standards, manual inspection of the parts had been instituted between each step in the process. Manual inspection of the parts following rinsing, but prior to plating however, nullified an otherwise effective rinsing procedure by introducing residue from the inspectors fingertips. In an attempt to find the source of the problem, the plating vendor initiated a more rigorous manual inspection which only resulted in more defects from greater amounts of handling. Interestingly, the original plating operation with manual inspection presented no problems when started in early January. Blister defects only began to appear as ambient temperatures rose in early summer, reaching a peak in late July when persperation and exuded oils from the inspectors fingertips increased.</p>
<p><strong>“Micro Soccer Balls”</strong></p>
<p>The root cause in our failure analysis of a gearbox transfer case was straight forward. The unit had been in service for only a short time before failure and was one of several cases which had failed in nearly identical circumstances. Gross abrasive wear of the bearings and gear teeth was obvious. What was less obvious was the source of the contaminant. SEM examination of debris from the gear case contained the expected wear debris from the gears and bearings, considering the degree of damage they exhibited. Also present, however, were numerous spherical particles exhibiting a morphology that resembled microscopic soccer balls (Figure 7).</p>
<p><a href="http://failure-analysis.info/wp-content/uploads/2010/07/7-micro-soccer-balls.jpg"><img class="aligncenter size-medium wp-image-103" title="7-micro-soccer-balls" src="http://failure-analysis.info/wp-content/uploads/2010/07/7-micro-soccer-balls-300x226.jpg" alt="7 micro soccer balls 300x226 Analyzing Contaminants, Stains and Debris – Part 2" width="300" height="226" /></a></p>
<p style="text-align: center;">Figure 7 – One of the many “micro soccer balls” found in the in the gearbox transfer case. 825X</p>
<p>Analysis of the spherical particle by EDS indicated a composition of iron with approximately 2% manganese. Metal will take on a spherical form only when it solidifies from a molten state free of any outside force, including that of gravity when on a horizontal surface. That fact limited our potential sources. Temperatures generated from friction during the failure sequence would not begin to approach the melting point of iron, so that eliminated an internal source. No melting or foundry facilities were present at the manufacturing site where the gearboxes were assembled, furthermore, the particles size and morphology was inconsistent with a foundry source. That left arc welding spatter which, based on our experience with previous analyses, was consistent with the particle size and morphology. The problem here was that no welding was performed in the fabrication of the gearbox and the manufacturing site performed only mechanical assembly operations. The contaminant particles, however, said otherwise. A review of the affected gearboxes production dates, and comparison to plant maintenance records eventually solved the mystery, revealing that a facility upgrade involving welding had been performed near the assembly line on the affected dates.</p>
<p><strong>Unknown Residue</strong></p>
<p>A manufacturer of aluminum high performance automotive pistons noticed a white residue on finished parts during the final inspection process. A review indicated that no changes in the manufacturing process or materials had been implemented, but despite an enhanced cleaning procedure the residue persisted. Piston samples exhibiting the white residue (Figure <img src='http://failure-analysis.info/wp-includes/images/smilies/icon_cool.gif' alt='8)' class='wp-smiley' title="Analyzing Contaminants, Stains and Debris – Part 2" /> were sent to MAI to determine its composition and source.</p>
<p><a href="http://failure-analysis.info/wp-content/uploads/2010/07/8-unknown-residue.jpg"><img class="aligncenter size-medium wp-image-104" title="8-unknown-residue" src="http://failure-analysis.info/wp-content/uploads/2010/07/8-unknown-residue-300x234.jpg" alt="8 unknown residue 300x234 Analyzing Contaminants, Stains and Debris – Part 2" width="300" height="234" /></a></p>
<p style="text-align: center;">Figure 8 – White residue deposit on the piston at the ring lands. 4.0X</p>
<p>Examination of the residue by SEM revealed a crystalline morphology as shown in Figure 9. Chemical analysis by EDS (Figure 10) indicated phosphorus, potassium and oxygen as the primary components of the residue with trace levels of carbon, sulfur and other elements.</p>
<p><a href="http://failure-analysis.info/wp-content/uploads/2010/07/9-acicular-crystalline-morphology.jpg"><img class="aligncenter size-medium wp-image-105" title="9-acicular-crystalline-morphology" src="http://failure-analysis.info/wp-content/uploads/2010/07/9-acicular-crystalline-morphology-300x211.jpg" alt="9 acicular crystalline morphology 300x211 Analyzing Contaminants, Stains and Debris – Part 2" width="300" height="211" /></a></p>
<p style="text-align: center;">Figure 9 – White residue on the piston exhibited an acicular crystalline morphology. 1000X</p>
<p><a href="http://failure-analysis.info/wp-content/uploads/2010/07/10-EDS-analysis-.jpg"><img class="aligncenter size-medium wp-image-106" title="10-EDS-analysis-" src="http://failure-analysis.info/wp-content/uploads/2010/07/10-EDS-analysis--300x172.jpg" alt="10 EDS analysis  300x172 Analyzing Contaminants, Stains and Debris – Part 2" width="300" height="172" /></a></p>
<p style="text-align: center;">Figure 10 – EDS analysis of the residue showed oxygen (O), phosphorus (P) and potassium (K)<br />
as the main constituents. The aluminum (Al) is from the piston substrate.</p>
<p>The oxygen, phosphorus and potassium are characteristic of tribasic potassium phosphate, a common component of soaps and detergents. Analysis of the detergent used to clean the pistons following machining confirmed that this was the source of the residue. Persistent questions to vendor eventually produced an admission that a change had been made to the formulation of this detergent without notification of their customers. This change resulted in a less soluble reside which the original rinse procedure did not completely remove. An extension of the rinse time resolved the problem in the short term and got pistons shipped. An eventual change in detergent brought the rinse time, and production rate, back to the original schedule.</p>
<p>Read part 1 of <a title="analyzing contaminants" href="http://failure-analysis.info/2010/07/analyzing-contaminants-stains-and-debris-part-1/">Analyzing Contaminants, Stains and Debris</a></p>
]]></content:encoded>
			<wfw:commentRss>http://failure-analysis.info/2010/07/analyzing-contaminants-stains-and-debris-part-2/feed/</wfw:commentRss>
		<slash:comments>0</slash:comments>
		</item>
		<item>
		<title>Analyzing Contaminants, Stains and Debris – Part 1</title>
		<link>http://failure-analysis.info/2010/07/analyzing-contaminants-stains-and-debris-part-1/</link>
		<comments>http://failure-analysis.info/2010/07/analyzing-contaminants-stains-and-debris-part-1/#comments</comments>
		<pubDate>Fri, 02 Jul 2010 16:54:56 +0000</pubDate>
		<dc:creator>Rob</dc:creator>
				<category><![CDATA[Contaminant Analysis]]></category>
		<category><![CDATA[debris]]></category>
		<category><![CDATA[featured]]></category>
		<category><![CDATA[stains]]></category>

		<guid isPermaLink="false">http://failure-analysis.info/?p=93</guid>
		<description><![CDATA[The impact of contaminants, stains or debris can range from nuisance to root cause of catastrophic failure. The nature of these materials presents some special analytical challenges. First, only extremely small amounts of material are usually present and available for analysis. Second, they typically result from an unintended and therefore undocumented variable in the manufacturing [...]]]></description>
			<content:encoded><![CDATA[<p>The impact of contaminants, stains or debris can range from nuisance to root cause of catastrophic failure. The nature of these materials presents some special analytical challenges. First, only extremely small amounts of material are usually present and available for analysis. Second, they typically result from an unintended and therefore undocumented variable in the manufacturing process or site, conditions encountered during shipping, or the service environment. This means the source can be a complete unknown, unrelated to any industrial use. Fingerprints, HVAC residue from filters or lubricants, insect excretions, road or sea salt which has found its way into “sealed” shipping containers, the almost microscopic remains of lunch sticking to an assemblers fingertips, combustion residue from nearby idling trucks, power plant smoke stacks or food processors, that “special” can of spray lube an employee keeps in his tool box. The list is literally endless, you are starting from square one, anything is possible and there is no such thing as “typical”.</p>
<p>The objective in analyzing contaminants is the identification and elimination or isolation of their source. Techniques used make this identification include Optical Stereomicroscopy, Scanning Electron Microscopy (SEM) and Energy Dispersive  X-Ray Spectroscopy (EDS). The accompanying case studies describe a selection of contaminant analyses performed here at Metallurgical Associates. Part 2 of this discussion will describe examples of the analysis of contaminants fro a variety of sources.</p>
<p>Read part 2 of <a title="analyzing stains and debris" href="http://failure-analysis.info/2010/07/analyzing-contaminants-stains-and-debris-part-1/">Analyzing Contaminants, Stains and Debris</a>.</p>
]]></content:encoded>
			<wfw:commentRss>http://failure-analysis.info/2010/07/analyzing-contaminants-stains-and-debris-part-1/feed/</wfw:commentRss>
		<slash:comments>1</slash:comments>
		</item>
		<item>
		<title>Microbiologically Induced Corrosion &#8211; Prevention and Analysis</title>
		<link>http://failure-analysis.info/2010/06/microbiologically-induced-corrosion-prevention-and-analysis/</link>
		<comments>http://failure-analysis.info/2010/06/microbiologically-induced-corrosion-prevention-and-analysis/#comments</comments>
		<pubDate>Fri, 04 Jun 2010 20:10:24 +0000</pubDate>
		<dc:creator>Rob</dc:creator>
				<category><![CDATA[Corrosion Analysis]]></category>
		<category><![CDATA[corrosion prevention]]></category>
		<category><![CDATA[MIC]]></category>
		<category><![CDATA[Microbiologically Induced Corrosion]]></category>

		<guid isPermaLink="false">http://failure-analysis.info/?p=65</guid>
		<description><![CDATA[The first line of defense against Microbiologically Induced Corrosion (MIC) is cleanliness. General corrosion prevention techniques are a good starting point since once corrosion begins, the introduction of MIC producing bacteria will greatly accelerate the process. Once bacteria are established, both anaerobic bacteria which “tunnel” into metal, and other forms which adhere under biofilms, are [...]]]></description>
			<content:encoded><![CDATA[<p>The first line of defense against Microbiologically Induced Corrosion (MIC) is cleanliness. General corrosion prevention techniques are a good starting point since once corrosion begins, the introduction of MIC producing bacteria will greatly accelerate the process. Once bacteria are established, both anaerobic bacteria which “tunnel” into metal, and other forms which adhere under biofilms, are extremely difficult to completely remove from the affected system. Water and other fluids should be monitored for solids and debris content. These contaminants provide nutrients to bacteria, accelerating their proliferation. Filtering of fluids is useful in this respect. Water content in fuels, lubricants and similar products should be monitored and removed when excessive levels are reached.</p>
<p>Material substitution is of limited value since, as noted, MIC affects almost all industrial metals. There are, however, several materials which are impervious or resistant to MIC where cost and compatibility justify their use. These materials are generally extremely expensive and in some cases, such as titanium, require specialized fabrication methods. In the case of underground pipelines and other fluid transport and storage systems, alternate non-metallic materials such as PVC have significantly limited MIC where these materials can be substituted. Local building codes, however, often exclude this option in structural applications.</p>
<p>Design to minimize low-flow areas, crevices, welds, etc. can reduce the likelihood of MIC but there are severe limitations to how far this approach can be taken in the design and manufacture of practical systems. Biocides are widely used to treat incoming water. These, however, are highly toxic and expensive, and require regular monitoring of concentration. Their toxicity and potential contaminative effect precludes their use in any food products system and with many process fluids.</p>
<p>The parameters in which MIC can occur are extremely varied and include multiple bacteria species, a broad range of affected materials and almost endless environmental diversity. As a result, MIC prevention and mitigation is equally varied. Accurate analysis of the cause and effects of each individual MIC failure is an essential first step in selecting from this range of solutions.<strong> </strong></p>
<p><strong>Microbiologically Induced Corrosion (MIC) Failures</strong></p>
<p><strong>MIC Failure Example 1</strong></p>
<p><a href="http://failure-analysis.info/wp-content/uploads/2010/06/MIC-Failure-1.jpg"><img class="aligncenter size-medium wp-image-66" title="MIC-Failure-1" src="http://failure-analysis.info/wp-content/uploads/2010/06/MIC-Failure-1-300x225.jpg" alt="MIC Failure 1 300x225 Microbiologically Induced Corrosion   Prevention and Analysis" width="300" height="225" /></a></p>
<p>This sequence shows several steps in the analysis of pitting corrosion in stainless steel tubing from a water bottling plant. The plant processes purified water, normally a media relatively immune to MIC. However, hydrostatic testing, performed during installation of the process piping, introduced anaerobic bacteria which adhered to several tube ID welds and adjacent areas, resulting in MIC and perforation of the tubes (above).</p>
<p><a href="http://failure-analysis.info/wp-content/uploads/2010/06/MIC-Failure-2.jpg"><img class="aligncenter size-medium wp-image-67" title="MIC-Failure-2" src="http://failure-analysis.info/wp-content/uploads/2010/06/MIC-Failure-2-300x287.jpg" alt="MIC Failure 2 300x287 Microbiologically Induced Corrosion   Prevention and Analysis" width="300" height="287" /></a></p>
<p>The perforations were examined using a Scanning Electron Microscope (SEM) which revealed biological adhesions in and around the pits. Several entries leading to apparent sub-surface voids were also observed (shown at arrows).</p>
<p><a href="http://failure-analysis.info/wp-content/uploads/2010/06/MIC-Failure-3.jpg"><img class="aligncenter size-medium wp-image-68" title="MIC-Failure-3" src="http://failure-analysis.info/wp-content/uploads/2010/06/MIC-Failure-3-300x225.jpg" alt="MIC Failure 3 300x225 Microbiologically Induced Corrosion   Prevention and Analysis" width="300" height="225" /></a></p>
<p>Micro-chemical analysis of the biological adhesions, by Energy Dispersive Spectroscopy (EDS), identified high levels of carbon (C), oxygen (O) and sulfur (S). These elements are consistent with sulfur reducing and oxidizing anaerobic bacteria species implicated in MIC.</p>
<p><a href="http://failure-analysis.info/wp-content/uploads/2010/06/MIC-Failure-4.jpg"><img class="aligncenter size-medium wp-image-69" title="MIC-Failure-4" src="http://failure-analysis.info/wp-content/uploads/2010/06/MIC-Failure-4-300x225.jpg" alt="MIC Failure 4 300x225 Microbiologically Induced Corrosion   Prevention and Analysis" width="300" height="225" /></a></p>
<p>Polished cross sections through the pits revealed internal cavities in the 0.060” thick tube wall, again, a hallmark of anaerobic bacteria which adhered to the tube ID surface and migrated to these oxygen depleted cavities formed by corrosive attack from their acidic bi-products. Because MIC usually initiates at the ID of tubing, extensive corrosion and eventual perforation occur before any visible evidence of attack is apparent externally.</p>
<p><strong>MIC Failure Example 2</strong></p>
<p><a href="http://failure-analysis.info/wp-content/uploads/2010/06/MIC-Failure-5.jpg"><img class="aligncenter size-medium wp-image-72" title="MIC-Failure-5" src="http://failure-analysis.info/wp-content/uploads/2010/06/MIC-Failure-5-300x216.jpg" alt="MIC Failure 5 300x216 Microbiologically Induced Corrosion   Prevention and Analysis" width="300" height="216" /></a></p>
<p>“Weeping” of fluid from systems is a precursor to full blown perforation by MIC. The source of this “weeping” is often a subtle discoloration of the tube or vessel surface as shown at the center of the circled area.</p>
<p><a href="http://failure-analysis.info/wp-content/uploads/2010/06/MIC-Failure-6.jpg"><img class="aligncenter size-medium  wp-image-73" title="MIC-Failure-6" src="http://failure-analysis.info/wp-content/uploads/2010/06/MIC-Failure-6-300x239.jpg" alt="MIC Failure 6 300x239 Microbiologically Induced Corrosion   Prevention and Analysis" width="300" height="239" /></a></p>
<p>Examination of these features by Scanning Electron Microscopy reveals fine micro-pitting and a “sponge” like morphology as the interior MIC attack nears the outer surface.</p>
<p><a href="http://failure-analysis.info/wp-content/uploads/2010/06/MIC-Failure-7.jpg"><img class="aligncenter size-medium wp-image-74" title="MIC-Failure-7" src="http://failure-analysis.info/wp-content/uploads/2010/06/MIC-Failure-7-300x267.jpg" alt="MIC Failure 7 300x267 Microbiologically Induced Corrosion   Prevention and Analysis" width="300" height="267" /></a></p>
<p>Probing of this “sponge” like surface collapsed the thin crust of remaining metal, exposing the sub-surface cavity created by anaerobic bacteria and their sulfuric acid bi-products.</p>
<p><a href="http://failure-analysis.info/wp-content/uploads/2010/06/MIC-Failure-8.jpg"><img class="aligncenter size-medium wp-image-75" title="MIC-Failure-8" src="http://failure-analysis.info/wp-content/uploads/2010/06/MIC-Failure-8-300x218.jpg" alt="MIC Failure 8 300x218 Microbiologically Induced Corrosion   Prevention and Analysis" width="300" height="218" /></a></p>
<p>A cross section of the discolored feature reveals the extent of corrosive MIC damage which has penetrated completely through the tube wall thickness.</p>
<p><strong>MIC Failure Example 3</strong></p>
<p><a href="http://failure-analysis.info/wp-content/uploads/2010/06/MIC-Failure-9.jpg"><img class="aligncenter size-medium wp-image-76" title="MIC-Failure-9" src="http://failure-analysis.info/wp-content/uploads/2010/06/MIC-Failure-9-300x223.jpg" alt="MIC Failure 9 300x223 Microbiologically Induced Corrosion   Prevention and Analysis" width="300" height="223" /></a></p>
<p>Pitting and general corrosion are both associated with MIC, sometimes in the same corrosion failure. The interior of this carbon steel storage tank exhibits extensive general corrosion.</p>
<p><a href="http://failure-analysis.info/wp-content/uploads/2010/06/MIC-Failure-10.jpg"><img class="aligncenter size-medium wp-image-77" title="MIC-Failure-10" src="http://failure-analysis.info/wp-content/uploads/2010/06/MIC-Failure-10-300x270.jpg" alt="MIC Failure 10 300x270 Microbiologically Induced Corrosion   Prevention and Analysis" width="300" height="270" /></a></p>
<p>Examination by Scanning Electron Microscopy revealed numerous tubercles on the corroded tank ID surface. Tubercles are found in association with MIC producing iron oxidizing anaerobic bacteria.</p>
<p><a href="http://failure-analysis.info/wp-content/uploads/2010/06/MIC-Failure-11.jpg"><img class="aligncenter size-medium wp-image-78" title="MIC-Failure-11" src="http://failure-analysis.info/wp-content/uploads/2010/06/MIC-Failure-11-300x229.jpg" alt="MIC Failure 11 300x229 Microbiologically Induced Corrosion   Prevention and Analysis" width="300" height="229" /></a></p>
<p>The interface of the tubercle with the metal substrate beneath it offers an oxygen depleted environment that is ideal for anaerobic MIC bacteria. Ultrasonic cleaning of a section of the corroded tank to remove the tubercles revealed small deep pits suggesting connected sub-surface cavities consistent with MIC by sulfur reducing bacteria.</p>
<p><a href="http://failure-analysis.info/wp-content/uploads/2010/06/MIC-Failure-12.jpg"><img class="aligncenter size-medium wp-image-79" title="MIC-Failure-12" src="http://failure-analysis.info/wp-content/uploads/2010/06/MIC-Failure-12-300x225.jpg" alt="MIC Failure 12 300x225 Microbiologically Induced Corrosion   Prevention and Analysis" width="300" height="225" /></a></p>
<p>Cross sections of the tank confirm anaerobic MIC bacterial activity by the presence of characteristic sub-surface voids. This failure demonstrates the symbiotic relationship often found between two or more MIC implicated bacterial species, producing two corrosion modes (general and pitting) in a single corrosion failure.</p>
<p>See Part 1 of this series &#8211; <a title="biological corrosion of metals" href="http://failure-analysis.info/2010/06/biological-corrosion-of-metals/">Biological Corrosion of Metals</a></p>
<p>See Part 2 of this series &#8211; <a title="microbiologically induced corrosion" href="http://failure-analysis.info/2010/06/microbiologically-induced-corrosion/">Microbiologically Induced Corrosion</a></p>
]]></content:encoded>
			<wfw:commentRss>http://failure-analysis.info/2010/06/microbiologically-induced-corrosion-prevention-and-analysis/feed/</wfw:commentRss>
		<slash:comments>1</slash:comments>
		</item>
		<item>
		<title>Microbiologically Induced Corrosion</title>
		<link>http://failure-analysis.info/2010/06/microbiologically-induced-corrosion/</link>
		<comments>http://failure-analysis.info/2010/06/microbiologically-induced-corrosion/#comments</comments>
		<pubDate>Thu, 03 Jun 2010 15:10:19 +0000</pubDate>
		<dc:creator>Rob</dc:creator>
				<category><![CDATA[Corrosion Analysis]]></category>
		<category><![CDATA[biological corrosion]]></category>
		<category><![CDATA[MIC]]></category>
		<category><![CDATA[Microbiologically Induced Corrosion]]></category>

		<guid isPermaLink="false">http://failure-analysis.info/?p=62</guid>
		<description><![CDATA[Microbiologically Induced Corrosion (MIC) occurs as both general corrosion and pitting corrosion, though localized pitting is the more definitive form and more likely to result in dramatic system failures. Low flow areas in circulating systems such as heat exchangers and process piping are particularly susceptible since these “stalled flow” locations provide bacteria with the opportunity [...]]]></description>
			<content:encoded><![CDATA[<p>Microbiologically Induced Corrosion (MIC) occurs as both general corrosion and pitting corrosion, though localized pitting is the more definitive form and more likely to result in dramatic system failures. Low flow areas in circulating systems such as heat exchangers and process piping are particularly susceptible since these “stalled flow” locations provide bacteria with the opportunity to attach to the tube or pipe surface. At both microscopic and macroscopic features, fluid flow “stalling” occurs at any crevice, joint, weld, or imperfection and these are typical locations for MIC. Interrupted flow in circulating fluid systems such as weekend, over night, or even brief maintenance shutdowns, also provides the opportunity for bacterial adhesions and the initiation of MIC. Once the bacteria are established, the corrosion process will proceed even after flow is restored. Hydro-static testing, in which a system is filled with fluid, pressurized, leak tested and drained – but often not completely dried – is a sequence repeatedly seen in the initiation of MIC failures. This testing usually immediately precedes placing the system in service, and failure may not occur for several months. When failure does eventually occur, the hydro-static test and stagnant fluid residue are often overlooked and the cause of failure is misdiagnosed as chloride induced corrosion.</p>
<p>Static fluid systems such as sumps and storage tanks are receptive environments for MIC. Corners, fittings, joints and welds are again vulnerable and in the case of fuels and non-water soluble fluids, the interface between the fluid and any water contaminant is particularly susceptible. MIC in underground storage tanks and pipelines, particularly in moist clay soils, has been widely observed despite protective tar, asphalt or polymeric coatings. While effective in preventing conventional corrosion, any de-lamination or bond failure of the coating provides an ideal bacterial growth environment.</p>
<p>Virtually all industrial metal alloys are subject to MIC, with the exception of titanium alloys. Testing suggests that the few stainless steel alloys containing molybdenum at levels of 6% or more are also highly resistant to MIC. These limitations severely restrict material substitution as a strategy to resolve MIC failures.</p>
<p><strong>Carbon Steels</strong> – Generally more susceptible to conventional corrosion processes, carbon steels are also widely affected by a broad range of MIC implicated bacteria. Considerations of cost and ease of fabrication make carbon steel the material of choice in many water storage and transport applications, as well as the most widely reported material in MIC failures. Protective coatings generally have limited preventive value.</p>
<p><strong>Stainless Steels</strong> – These alloys develop tough chromium oxide surface layers from which they derive their corrosion resistance. Once the oxide layer is breached, however, they are particularly vulnerable to both conventional and MIC corrosion. Welds are highly susceptible due to potential alloy inhomogenaity. Highly stressed components are potential initiation sites for MIC induced stress corrosion cracking.</p>
<p><strong>Aluminum Alloys</strong> – One of the earliest high profile cases of MIC was of aluminum jet aircraft fuel tanks in the 1950’s. Water contamination in the kerosene based fuel and condensation in the tanks provided the media in which the bacteria multiplied. Research indicates some bacteria species may utilize kerosene and other fossil fuels as a nutrient source. Since this landmark case, MIC has been widely recognized as a significant problem in both tank and structural aircraft components.</p>
<p><strong>Copper Alloys</strong> – Typically, higher alloy content lowers the corrosion resistance of copper alloys, although relatively pure copper is also susceptible to MIC. Copper and copper alloys are effected by a wide range of microbial bi-products including carbon dioxide, hydrogen sulfide, and organic and inorganic acids. Cold worked or stressed copper alloy components are especially susceptible to stress corrosion cracking from ammonia and the bacteria that generate it. Selective corrosion, such as de-zincification in brass alloys, has also been observed in MIC failures.</p>
<p><strong>Nickel Alloys </strong>– These alloys are often used in high pressure, high flow rate applications such as pumps, turbine blades, valves and evaporators. Nickel alloy components in these systems are vulnerable to MIC during shut down intervals and stagnant water conditions. Nickel-chromium alloys exhibit a degree of resistance to MIC.</p>
<p>See Part 1 of this series &#8211; <a title="biological corrosion of metals" href="../2010/06/biological-corrosion-of-metals/">Biological  Corrosion of Metals</a></p>
<p>See Part 3 of this series &#8211; <a title="microbiologically induced corrosion prevention and analysis" href="http://failure-analysis.info/2010/06/microbiologically-induced-corrosion-prevention-and-analysis/">Microbiologically Induced Corrosion Prevention and Analysis</a></p>
]]></content:encoded>
			<wfw:commentRss>http://failure-analysis.info/2010/06/microbiologically-induced-corrosion/feed/</wfw:commentRss>
		<slash:comments>1</slash:comments>
		</item>
		<item>
		<title>Biological Corrosion of Metals</title>
		<link>http://failure-analysis.info/2010/06/biological-corrosion-of-metals/</link>
		<comments>http://failure-analysis.info/2010/06/biological-corrosion-of-metals/#comments</comments>
		<pubDate>Wed, 02 Jun 2010 16:59:58 +0000</pubDate>
		<dc:creator>Rob</dc:creator>
				<category><![CDATA[Corrosion Analysis]]></category>
		<category><![CDATA[biological corrosion]]></category>
		<category><![CDATA[featured]]></category>
		<category><![CDATA[metal corrosion]]></category>

		<guid isPermaLink="false">http://failure-analysis.info/?p=55</guid>
		<description><![CDATA[Desulfovibrio vulgaris, a sulfur reducing bacteria, generate hydrogen sulfide as a metabolic bi-product. This species has been implicated in MIC – Microbiologically Induced Corrosion – in iron, steel, stainless steel, aluminum, zinc and copper alloys. The cost of corrosion to the US economy is estimated at 4.2% of the Gross National Product according to a [...]]]></description>
			<content:encoded><![CDATA[<p><a href="http://failure-analysis.info/wp-content/uploads/2010/06/biological-corrosion.jpg"><img class="alignright size-medium wp-image-56" title="biological-corrosion" src="http://failure-analysis.info/wp-content/uploads/2010/06/biological-corrosion-300x222.jpg" alt="biological corrosion 300x222 Biological Corrosion of Metals" width="300" height="222" /></a>Desulfovibrio vulgaris, a sulfur reducing bacteria, generate hydrogen sulfide as a metabolic bi-product. This species has been implicated in MIC – Microbiologically Induced Corrosion – in iron, steel, stainless steel, aluminum, zinc and copper alloys.</p>
<p>The cost of corrosion to the US economy is estimated at 4.2% of the Gross National Product according to a recent study. That amounts to over $350 billion annually which, until this year, exceeds the cost of all oil imports into the US.</p>
<p>Corrosion is the most common and costly failure mode impacting engineered and structural materials, yet it tends to be accepted as inevitable precisely because it is so pervasive. The same study, however, indicates that 40% of these costs, or $140 billion, could be saved through the application of existing practices and technologies. Although numbers of this magnitude tend to be overwhelming, they translate into real costs and lost savings by industry, right down to individual manufacturers and product end users.</p>
<p>The term “corrosion” describes a number of processes driven by a wide range of electro-chemical factors. At the root of these is the inherent instability, at the atomic level, of most industrial metals which predisposes them to return to their naturally occurring form, oxides.</p>
<p>One of the more unusual forms of corrosion results from the interaction of bacteria with a wide range of metals and alloys. Microbiologically Induced Corrosion (MIC) “technically” functions as an accelerant to more conventional corrosion processes. The rate of acceleration, however, may be from 10 to 1000 times conventional corrosion rates, requiring that MIC be addressed as a distinct corrosion process, from a practical standpoint.</p>
<p>MIC initiates and propagates primarily by two processes. The first is the formation of corrosion cells on a metal surface. Colonies of micro-organisms generate sticky biofilms which adhere them to their host surface and create a micro-environment that is significantly different from the surrounding metal. Variations in dissolved oxygen, pH, and organic and inorganic compounds in these micro-environments result in electrical potential differences with the surrounding metal, producing highly active corrosion cells.</p>
<p>The second is by direct chemical attack.  The metabolic by-products of many micro-organisms are highly corrosive. Two related organisms, sulfur reducing bacteria (Disulfovibrio) and sulfur oxidizing bacteria (Thiobacillus thiooxidans), produce hydrogen sulfide and sulfuric acid respectively. Localized sulfuric acid concentrations as high as 10% have been observed from these by-products. Other bacteria species produce a wide range of organic acids such as acetic acid, as well as ammonia.</p>
<p>Both aerobic bacteria, which thrive in an oxygenated environment, and anaerobic bacteria, which thrive in a minimal or non-oxygen environment have been documented in MIC. In some cases, these two bacterial types share a symbiotic relationship as aerobic bacteria deposit biofilms under which an oxygen depleted zone is formed at the metal interface. This oxygen depleted zone then becomes an ideal environment for the growth of anaerobic bacteria colonies.</p>
<p>The formation of tubercles is also often associated with MIC.  Tubercles resemble blisters of corrosion product and are initiated from biofilm deposits and iron oxidizing bacteria, particularly at low flow velocity areas in fluid piping systems. The growth and decomposition cycle of the tubercle releases sulfates and provides a site for anaerobic sulfate reducing bacteria on the interior of the blister. Tubercles also form an efficient oxygen concentration cell, dissolving iron under the blister.  Unchecked tubercle growth in fluid transport systems will severely limit or even completely block fluid flow.</p>
<p style="text-align: center;"><a href="http://failure-analysis.info/wp-content/uploads/2010/06/biological-corrosion-2.jpg"><img class="size-medium wp-image-57 aligncenter" title="biological-corrosion-2" src="http://failure-analysis.info/wp-content/uploads/2010/06/biological-corrosion-2-300x120.jpg" alt="biological corrosion 2 300x120 Biological Corrosion of Metals" width="300" height="120" /></a></p>
<p style="text-align: center;">Click image to enlarge.</p>
<p style="text-align: left;">Classic hallmark of a common MIC failure type. The cross-section above shows a Type 304 stainless steel heat exchanger tube that failed by MIC at the longitudinal seam weld, perforating the 0.065” thick tube wall.  MIC began at the tube ID due to an anaerobic bacteria species introduced through incomplete drying following hydrostatic testing.</p>
<p style="text-align: left;">Contact of the metal’s surface with water is a pre-condition to MIC. Since the bacteria species responsible for MIC pose no human health risk, “safe” drinking water systems are just as much at risk as non-potable water systems. Cooling systems and heat exchangers, wells, fire and agricultural automatic sprinkler systems and liquid storage tanks are among the more obvious potential sites for MIC to develop. However, fluid products not normally associated with water such as gasoline, oil and machining and cutting lubricants all contain at least trace levels of water which are sufficient to support bacteria that initiate MIC. Virtually all processed fluid products including food and beverage, petrochemical and other commercial and industrial products also contain varying amounts of water and are susceptible to MIC.</p>
<p style="text-align: left;">See Part 2 of this series &#8211; <a title="microbiologically induced  corrosion" href="../2010/06/microbiologically-induced-corrosion/">Microbiologically  Induced Corrosion</a></p>
<p style="text-align: left;">
<p>See Part 3 of this series &#8211; <a title="microbiologically induced  corrosion prevention and analysis" href="http://failure-analysis.info/2010/06/microbiologically-induced-corrosion-prevention-and-analysis/">Microbiologically  Induced Corrosion Prevention and Analysis</a></p>
]]></content:encoded>
			<wfw:commentRss>http://failure-analysis.info/2010/06/biological-corrosion-of-metals/feed/</wfw:commentRss>
		<slash:comments>0</slash:comments>
		</item>
		<item>
		<title>Analyzing Material Fatigue</title>
		<link>http://failure-analysis.info/2010/05/analyzing-material-fatigue/</link>
		<comments>http://failure-analysis.info/2010/05/analyzing-material-fatigue/#comments</comments>
		<pubDate>Wed, 05 May 2010 04:24:55 +0000</pubDate>
		<dc:creator>Rob</dc:creator>
				<category><![CDATA[Failure Analysis]]></category>
		<category><![CDATA[material fatigue]]></category>
		<category><![CDATA[scanning electron microscopy]]></category>

		<guid isPermaLink="false">http://failure-analysis.info/?p=21</guid>
		<description><![CDATA[A variety of analytical tools and techniques are used to identify fatigue fractures and their root cause. These include macroscopic examination, microstructural analysis, hardness testing, chemical analysis, microprobe chemical analysis and scanning electron microscopy (SEM). There are three stages in the life of a fatigue failure; 1. Initiation, 2. Crack Growth (propagation), and 3. Final [...]]]></description>
			<content:encoded><![CDATA[<p>A variety of analytical tools and techniques are used to identify fatigue fractures and their root cause. These include macroscopic examination, microstructural analysis, hardness testing, chemical analysis, microprobe chemical analysis and scanning electron microscopy (SEM).</p>
<p><a href="http://failure-analysis.info/wp-content/uploads/2010/05/scanning-electron-microscopy-1.jpg"><img class="aligncenter size-medium wp-image-23" title="scanning-electron-microscopy-1" src="http://failure-analysis.info/wp-content/uploads/2010/05/scanning-electron-microscopy-1-300x234.jpg" alt="scanning electron microscopy" width="300" height="234" /></a></p>
<p>There are three stages in the life of a fatigue failure; 1. Initiation, 2. Crack Growth (propagation), and 3. Final Fracture. These stages are illustrated in the SEM image of a fractured rectangular wire above. The Initiation is indicated by the large red arrow at the lower left. The area of progressive Crack Growth extends from this arrow to the line indicated by the three smaller red arrows. Final Fracture, the point at which the remaining intact cross section of the wire could not sustain the next cyclic stress load – “the straw that breaks the camels back” – and complete fracture occurred, is the light area above the three arrows. This fracture is an example of bending fatigue (in one direction) initiating from a single point of origin.</p>
<p><a href="http://failure-analysis.info/wp-content/uploads/2010/05/reverse-bending-fatigue-2.jpg"><img class="aligncenter size-medium wp-image-24" title="reverse-bending-fatigue-2" src="http://failure-analysis.info/wp-content/uploads/2010/05/reverse-bending-fatigue-2-300x234.jpg" alt="reverse bending fatigue" width="300" height="234" /></a></p>
<p>The fractured crane lifting hook above is an example of reverse bending fatigue (back and forth in two directions). In this case, the major bending stress was applied from the bottom of the fracture as oriented in this photo, and a minor stress from the top. The darker gray area indicates final fracture in a single stress cycle. The thin horizontal band at mid fracture indicates a significant “jump” in the fracture progression that occurred in the cycle proceeding final fracture which almost, but not quite, resulted in complete fracture. This fatigue fracture initiated from multiple origins. Multiple origins are indicated by the steps, or “ratchet marks”, at the outer diameter of the fracture indicated by the arrows. Ratchet marks occur when multiple fatigue cracks initiate at slightly different planes on a component’s surface. As these multiple cracks progress into the component, they eventually join into a single fracture plane as show above.</p>
<p><a href="http://failure-analysis.info/wp-content/uploads/2010/05/nascar-suspension-failure-3.jpg"><img class="aligncenter size-medium wp-image-25" title="nascar-suspension-failure-3" src="http://failure-analysis.info/wp-content/uploads/2010/05/nascar-suspension-failure-3-300x190.jpg" alt="nascar suspension failure" width="300" height="190" /></a></p>
<p><a href="http://failure-analysis.info/wp-content/uploads/2010/05/nascar-suspension-failure-4.jpg"><img class="aligncenter size-medium wp-image-26" title="nascar-suspension-failure-4" src="http://failure-analysis.info/wp-content/uploads/2010/05/nascar-suspension-failure-4-300x220.jpg" alt="nascar suspension failure" width="300" height="220" /></a></p>
<p>Rachet marks resulting from multiple fatigue origin locations are shown at high magnification in these images taken on our Scanning Electron Microscope (SEM). Fatigue cracking penetrated only a short distance into this NASCAR Racing suspension component before it failed completely in a single load cycle. As a result, the multiple origin fatigue cracks never progressed far enough to coalesce into a single fracture plane. Several of the individual origin sites are indicated by arrows.</p>
<p><a href="http://failure-analysis.info/wp-content/uploads/2010/05/fatigue-fracture-5.jpg"><img class="aligncenter size-medium wp-image-27" title="fatigue-fracture-5" src="http://failure-analysis.info/wp-content/uploads/2010/05/fatigue-fracture-5-300x254.jpg" alt="fatigue fracture" width="300" height="254" /></a></p>
<p>The diagonal bands exhibited by the fatigue fracture of this compressor connecting rod are commonly called “arrest lines”. These indicate a change in the frequency of cyclic stresses, such as “stop-start” sequences, changes in RPM, or variations in load. The initiation site at the crankshaft journal bore (arrow) is heavily damaged. This is not uncommon in fatigue failures. As the first location to crack, the initiation site is exposed to potential relative movement of the two sides of the crack during propagation. This presents a significant challenge to the analyst in determining the root cause of fatigue cracking.</p>
<p><a href="http://failure-analysis.info/wp-content/uploads/2010/05/fatigue-fracture-striation-6.jpg"><img class="aligncenter size-medium wp-image-28" title="fatigue-fracture-striation-6" src="http://failure-analysis.info/wp-content/uploads/2010/05/fatigue-fracture-striation-6-300x210.jpg" alt="fatigue fracture striation" width="300" height="210" /></a></p>
<p>Fatigue fractures exhibit distinct features, called striations, when viewed at high magnification using Scanning Electron Microscopy. Striations appear as relatively evenly spaced parallel lines. Each striation is actually a shallow crack that results from a single load, or stress, cycle. Repetition of these cycles produces an advancing repetition of shallow cracks as shown above in this fatigue fracture in a hydraulic valve body. This process is characterized by the term, “fatigue crack propagation”.</p>
<p><a href="http://failure-analysis.info/wp-content/uploads/2010/05/applied-load-fracture-7.jpg"><img class="aligncenter size-medium wp-image-29" title="applied-load-fracture-7" src="http://failure-analysis.info/wp-content/uploads/2010/05/applied-load-fracture-7-300x227.jpg" alt="applied load fracture" width="300" height="227" /></a></p>
<p><a href="http://failure-analysis.info/wp-content/uploads/2010/05/load-fracture-8.jpg"><img class="aligncenter size-medium wp-image-30" title="load-fracture-8" src="http://failure-analysis.info/wp-content/uploads/2010/05/load-fracture-8-300x211.jpg" alt="load fracture" width="300" height="211" /></a></p>
<p>The appearance, or morphology, of fatigue fracture striations varies depending on the magnitude and frequency of the applied load and the physical characteristics of the affected component such as hardness, microstructure and chemical composition of the alloy. These SEM images illustrate fatigue striations in an aluminum valve body (left) and an alloy steel high pressure hydraulic cylinder (right).</p>
<p><a href="http://failure-analysis.info/wp-content/uploads/2010/05/decarburization-9.jpg"><img class="aligncenter size-medium wp-image-31" title="decarburization-9" src="http://failure-analysis.info/wp-content/uploads/2010/05/decarburization-9-300x224.jpg" alt="decarburization 9 300x224 Analyzing Material Fatigue" width="300" height="224" /></a></p>
<p>In some cases, the root cause of a fatigue failure can only be discovered by an analysis of internal characteristics of a component at the crack location. In this example, a metallographic cross section revealed decarburization (dark phase at arrow) of the surface of a steering arm due to faulty heat treating. This carbon depleted layer has significantly reduced hardness and strength, as well as residual tensile stress, conditions highly conducive to fatigue crack initiation.</p>
<p><a href="http://failure-analysis.info/wp-content/uploads/2010/05/initiation-sites-for-fatigue-10.jpg"><img class="aligncenter size-medium  wp-image-32" title="initiation-sites-for-fatigue-10" src="http://failure-analysis.info/wp-content/uploads/2010/05/initiation-sites-for-fatigue-10-300x211.jpg" alt="initiation sites for fatigue" width="300" height="211" /></a></p>
<p><a href="http://failure-analysis.info/wp-content/uploads/2010/05/single-initiation-point-fatigue-11.jpg"><img class="aligncenter size-medium wp-image-33" title="single-initiation-point-fatigue-11" src="http://failure-analysis.info/wp-content/uploads/2010/05/single-initiation-point-fatigue-11-300x228.jpg" alt="single initiation point fatigue" width="300" height="228" /></a></p>
<p>Other types of internal defects which act as initiation sites for fatigue are apparent on the fracture surface. Examination of this brake return spring by SEM revealed fracture features which radiate from a single initiation point. Viewed at higher magnification, this initiation point exhibits a void containing a non-metallic inclusion which acted as a stress concentration.</p>
]]></content:encoded>
			<wfw:commentRss>http://failure-analysis.info/2010/05/analyzing-material-fatigue/feed/</wfw:commentRss>
		<slash:comments>0</slash:comments>
		</item>
		<item>
		<title>The Service Environment</title>
		<link>http://failure-analysis.info/2010/05/the-service-environment/</link>
		<comments>http://failure-analysis.info/2010/05/the-service-environment/#comments</comments>
		<pubDate>Wed, 05 May 2010 03:44:46 +0000</pubDate>
		<dc:creator>Rob</dc:creator>
				<category><![CDATA[Failure Analysis]]></category>

		<guid isPermaLink="false">http://failure-analysis.info/?p=17</guid>
		<description><![CDATA[Once a product leaves the factory you, the manufacturer, have lost control and all bets are off. Abuse and inadequate maintenance are leading sources of failure by fatigue, as well as other failure modes.  Failure of components or assemblies “up stream” from your product may introduce higher loads than the product or component was designed [...]]]></description>
			<content:encoded><![CDATA[<p>Once a product leaves the factory you, the manufacturer, have lost control and all bets are off. Abuse and inadequate maintenance are leading sources of failure by fatigue, as well as other failure modes.  Failure of components or assemblies “up stream” from your product may introduce higher loads than the product or component was designed to sustain. Service environments, such as road salts or ocean front installations may instigate corrosive attack, with corrosion pits providing a fatigue initiation sight. Analysis and identification of the root cause of fatigue failures in these cases is critical in educating  your customer in the appropriate use and maintenance of your product and getting them back on track as a satisfied customer.</p>
<p>Identifying the root cause of service environment initiated fatigue failures can be challenging. Some years ago, we provided analytical support on a lawsuit which was filed after an individual sustained a back injury when the metal leg of a “stacking chair” fractured. Stacking chairs are the type of institutional chairs you often see in school auditoriums, government office waiting rooms, etc. and are designed to be stacked, one upon the other, for more compact storage when not in use. This particular chair came from a college in Ohio. Our analysis proved low stress, high cycle fatigue as the failure mode. In other words, low magnitude stresses applied at high frequencies, in this case over a million cycles.</p>
<p>The chair had been in use for a relatively brief time, and even if it had seen longer service, it seemed unlikely that it had been sat in on a million occasions. This presented something of a mystery, as the failure mode was indisputable. Investigation of the service environment revealed that the chairs were used sporadically and when not in use, were stacked in a storeroom. The college staff was methodical in setting up the chairs in orderly rows in an adjacent auditorium, then stacking them from the same row end when they were no longer required, with the same chair ending up on the bottom of the stack before going back into storage. The stack was higher than the maximum specified by the manufacturer, providing a load in excess of the design limit. A survey of the area revealed that the storeroom was immediately above the main HVAC installation, the key and final piece of the puzzle. Vibration from the HVAC system, transmitted through the storeroom floor, and loads from the weight of chairs stacked in excess of the design limit provided the stresses required to initiate the fatigue crack. Once the crack grew to the point at which the remaining intact tubular leg could no longer sustain the load of a sitting person, final fracture occurred.</p>
<p>As with all failure analyses, the analyst must provide specific answers to three critical questions when evaluating a fatigue failure.</p>
<p>They are:</p>
<ol>
<li>How did it fail?</li>
<li>Why did it fail?  and</li>
<li>What will prevent future failures?</li>
</ol>
<p>If you have commissioned a failure analysis, and all three of these questions are not answered, all you have paid for is some interesting pictures and a possible lawsuit when your product fails again.</p>
<p>Read part 4 &#8211; <a title="analyzing material fatigue" href="http://failure-analysis.info/2010/05/analyzing-material-fatigue/">Analyzing Material Fatigue</a></p>
]]></content:encoded>
			<wfw:commentRss>http://failure-analysis.info/2010/05/the-service-environment/feed/</wfw:commentRss>
		<slash:comments>0</slash:comments>
		</item>
		<item>
		<title>Fatigue in the “Real World”</title>
		<link>http://failure-analysis.info/2010/04/fatigue-in-the-real-world/</link>
		<comments>http://failure-analysis.info/2010/04/fatigue-in-the-real-world/#comments</comments>
		<pubDate>Wed, 28 Apr 2010 03:21:24 +0000</pubDate>
		<dc:creator>Rob</dc:creator>
				<category><![CDATA[Failure Analysis]]></category>
		<category><![CDATA[material fatigue]]></category>

		<guid isPermaLink="false">http://failure-analysis.info/?p=10</guid>
		<description><![CDATA[In the “real world” fatigue usually – that’s usually, not always &#8211; initiates at a location that acts as a stress concentration, or focal point, to the stresses imposed on a component. Stress concentrations take a wide variety of forms. They include geometric features (such as holes, slots, corners and radii), rough areas of surface [...]]]></description>
			<content:encoded><![CDATA[<p>In the “real world” fatigue usually – that’s usually, not always &#8211; initiates at a location that acts as a stress concentration, or focal point, to the stresses imposed on a component. Stress concentrations take a wide variety of forms. They include geometric features (such as holes, slots, corners and radii), rough areas of surface finish, welds, corrosion pits, and microstructural defects such as inclusions.</p>
<p>The exception to “usually”, the cases where fatigue fractures initiate from component surfaces that are free of stress concentrations, typically result from one of two causes; under-design of the component, or abusive service conditions. Just as all materials have an ultimate tensile strength, they also have a <strong>fatigue strength</strong>, sometimes called the fatigue limit or endurance limit. Once a component is subjected to cyclic stresses that exceed this limit, fatigue fracture occurs.</p>
<p>Fatigue failures of this type are less common than fatigue failures initiating from stress concentrations. Usually components are intentionally over-designed to deal with stresses several times greater than what they would be subjected to in service as a safety margin.<br />
<strong><br />
Fatigue Crack Initiation – The Critical Event</strong></p>
<p>If the initiation stage can be prevented, fatigue fracture will not occur.  It sounds so obvious and simple. It’s not. As noted above, initiation is the most complex stage of fatigue fracture. A low magnitude load, which would have no effect whatsoever on a component in a single application, can be devastating when repeatedly applied as thousands or millions of cycles. The cumulative effect of these cyclic loads are microscopic “shifts” in the material’s structure which ultimately produce a “dislocation” – at this scale it is too small to be called a crack – and the focal point of stress concentration is born. Corners, holes, rough surface finish, welds and other features only accelerate the process.  To further complicate the issue, vibration harmonics, dampening of the system and the environment in which the component functions add a large unknown factor. Collectively, these affects become difficult to predict in the design stage.</p>
<p><strong>Confronting Fatigue – Attack and Defense</strong></p>
<p>From a practical standpoint, fatigue failures present a danger to you, the manufacturer, at three points in a components life. These are the design stage, the manufacturing process, and the service environment.</p>
<p><strong>Design</strong></p>
<p>The design engineer is the first line of defense against fatigue fracture.  He or she can’t prevent failures originating in the manufacturing process or service environment, but the designer lays the foundation of prevention.</p>
<p>In an ideal world, each design would be subjected to extensive stress calculations and fatigue testing.  In the real world this is rarely cost effective for non-critical components. Instead, accepted and “proven” parameters are applied.  These typically include safety margins which are more than adequate.  Typically, but not always.</p>
<p>Computer Aided Design (CAD), Finite Element Analysis (FEA) and a variety of other computer driven design and predictive technologies can greatly enhance the fatigue resistance of a component at the design stage.  But they can not prevent fatigue failures.  That’s because the next two threats of fatigue failure are beyond the designer’s control.</p>
<p><strong>The Manufacturing Process </strong></p>
<p>Manufacturing processes are a rich, though unintended, source of stress concentrations from which fatigue cracks can initiate.  The list is almost endless, and includes rough machined surfaces from dull tooling or excessive feeds and speeds, burrs from cutting or drilling operations, and insufficient chamfers or corner radiuses. Welds, even when technically faultless, provide geometric stress concentrations.  Defective welds and welding procedures may result in porosity and high hardness heat affected zones from which fatigue can initiate. Mechanical fasteners – bolts, screws, studs, and rivets- are highly prone to fatigue failure, either due to defects in the fastener itself, or to insufficient tightening torque during the assembly stage of the manufacturing process.</p>
<p>Care in manufacturing and a good quality control program will avert many of these potential sources of fatigue initiation.  However, despite the best quality control program, the manufacturer is often at the mercy of their raw material supplier. These suppliers may open the door to fatigue failure through castings which contain excessive porosity or  microstructural defects, mill products which are work hardened, forgings with undetected laps or seams, or gross non-metallic inclusions in any of these products. Appropriate specifications on outsourced stock and components are vital in guaranteeing their quality, but as with so many aspects of production, they are a compromise. Loose specs solicit low cost bids, but a potentially high percentage of defective products, while tight specs limit the number of vendors capable of meeting them and drive costs higher, cutting into profits.</p>
<p>Read part 3 &#8211; <a title="the service environment" href="http://failure-analysis.info/2010/05/the-service-environment/">The Service Environment</a></p>
]]></content:encoded>
			<wfw:commentRss>http://failure-analysis.info/2010/04/fatigue-in-the-real-world/feed/</wfw:commentRss>
		<slash:comments>0</slash:comments>
		</item>
		<item>
		<title>Fatigue and its Failure Analysis</title>
		<link>http://failure-analysis.info/2010/04/fatigue-and-its-failure-analysis/</link>
		<comments>http://failure-analysis.info/2010/04/fatigue-and-its-failure-analysis/#comments</comments>
		<pubDate>Thu, 22 Apr 2010 15:09:56 +0000</pubDate>
		<dc:creator>Rob</dc:creator>
				<category><![CDATA[Failure Analysis]]></category>
		<category><![CDATA[featured]]></category>

		<guid isPermaLink="false">http://failure-analysis.info/?p=1</guid>
		<description><![CDATA[On May 11th, 1842 the first major railroad disaster in history set off a chain of events which led to the discovery of the phenomenon that we now know as fatigue failure. The Paris – Versailles Express, hurtling down the tracks at the then astounding speed of 50 miles per hour, exploded in flames when [...]]]></description>
			<content:encoded><![CDATA[<p><a href="http://failure-analysis.info/wp-content/uploads/2010/04/failure-analysis-1.jpg"><img class="alignright size-medium wp-image-3" style="margin: 10px;" title="failure-analysis-1" src="http://failure-analysis.info/wp-content/uploads/2010/04/failure-analysis-1-300x189.jpg" alt="failure analysis 1 300x189 Fatigue and its Failure Analysis" width="300" height="189" /></a>On May 11th, 1842 the first major railroad disaster in history set off a chain of events which led to the discovery of the phenomenon that we now know as fatigue failure. The Paris – Versailles Express, hurtling down the tracks at the then astounding speed of 50 miles per hour, exploded in flames when the drive axle on the lead locomotive broke, digging its front end into the railbed. The second locomotive in the tandem drive set smashed into the firebox of the lead engine along with the first three cars, killing 57 passengers outright and injuring over a hundred more. It was the 1800’s equivalent of a jumbo jet crash, and the great scientific minds of the day focused their collective wisdom on perhaps the first major failure analysis in history. The result of their decade long investigation produced the beginnings of our understanding of fatigue.</p>
<p>Fatigue is the most common type of fracture in engineered components. Fatigue fractures are also particularly dangerous because they can occur under normal service conditions, with no warning that a progressively growing crack is developing until the final catastrophic failure. The component, whether it’s the outer aluminum skin of a commercial jet or a simple tubular chair leg, often <strong>appears</strong> to be perfectly sound with no visible distortion to warn of impending failure.</p>
<p>A <strong>technical</strong> understanding of fatigue requires a comprehensive knowledge of metallurgy, physics, and phenomena like plastic deformation, slip planes and dislocation theory. In fact, there are several competing theories on exactly what happens at a microscopic level when a fatigue crack initiates. But a <strong>practical</strong> understanding of the process is extremely beneficial and has direct application to its prevention, and the manufacturing environment, as discussed below.</p>
<p>To the non-technically inclined, the term “fatigue” suggests this type of failure is related to the age of a component, that the material is “tired”. In fact, fatigue fracture can occur within hours of a component going into service. Conversely, even large, highly stressed components can operate for decades with no fatigue cracking or failure.</p>
<p><strong>Fatigue fractures result from repeated, or cyclic, stresses.</strong> These stresses can take a variety of forms, such as bending (in one direction), reverse bending (back and forth in two directions), torsion (twisting in one or more axis) and rotation.  Regardless of the variation in direction, the stress on the component at the point of fatigue fracture is always tensile stress, in which the fracture initiation site is being “stretched”, or pulled in opposite directions. To illustrate this, visualize a tube which is being repeatedly bent in one direction. The side of the tube that is concave when it is bent is being compressed. The side of the tube which is convex is being “stretched”, or subjected to a tensile stress. This is the side on which a fatigue crack will initiate.</p>
<p><strong>Fatigue cracks initiate at stresses below the tensile strength of the material.</strong> Tensile strength is the stress, or load, at which a material breaks when pulled in two opposing directions. This load is a specific value for each metal alloy, varying somewhat depending on heat treating and other processing operations. These values are widely available in engineering reference manuals, typically expressed as pounds per square inch in American references. The fact that fatigue cracks can occur at stress levels below the tensile strength of a material is difficult to explain. Theories on this focus on physical and structural changes at the microscopic (0.0001” or less) area of crack initiation.</p>
<p><strong>Fatigue is a progressive fracture mechanism.</strong> Once a fatigue crack initiates, it is driven further into the component with each stress cycle. This crack growth process continues as long as the component is subjected to cyclic stress. Depending on the magnitude and frequency of these stresses, the crack may grow over time ranging from hours to years.  Eventually, the crack advances to a point where the remaining intact cross section of the component can not sustain the next cyclic stress load – “the straw that breaks the camels back” – and complete fracture of the component occurs.</p>
<p><strong>Read part 2</strong> &#8211; <a title="fatigue in the real world" href="http://failure-analysis.info/2010/04/fatigue-in-the-real-world/">Fatigue in the “Real World”</a></p>
]]></content:encoded>
			<wfw:commentRss>http://failure-analysis.info/2010/04/fatigue-and-its-failure-analysis/feed/</wfw:commentRss>
		<slash:comments>0</slash:comments>
		</item>
	</channel>
</rss>
